I would like to create a new account and transfer the PM number from the existing account to mine.
@slobidker transferring numbers between PM accounts is not done.
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The "Why" is the question to be answered. Once that is known then a possible solution can be offered to your query. But yes its possible but whether it's probable depends on many factors and it is against official policy to do so....but I can confirm it has been done on a case by case basis with a compelling reason and as always its YMMV.
If done you do have the correct procedure...activate a new account to move the desired phone # to and the old account gets assigned a new phone #.